HIGHLIGHTS
- who: α-Pyrone et al. from the Ural Federal University, Mira St, Ekaterinburg, Russian have published the paper: α‑pyrone and for the expedient of various scaffolds, in the Journal: (JOURNAL)
SUMMARY
Conferring to the biosynthetic origin the role of α-pyrone synthon was essential for the unusual oxygen pattern of highly strained macrocylic analogue 7 presence. The endo-bicyclolactone 18a was transformed into respective key cyclohexene derivatives 33-38 as illustrated in scheme 6. α-pyrone analogue was an imperative enophile synthon in the biogenetic Diels-Alder approach of various complex natural compounds. Subsequent, acid-catalyzed . . .
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