Nderivatives of perisubstituted dichalcogenide [fefe]hydrogenase mimics: towards photocatalytic dyads for hydrogen production

HIGHLIGHTS

  • who: Figliola and colleagues from the University of Birmingham have published the article: NDerivatives of periSubstituted Dichalcogenide [FeFe]Hydrogenase Mimics: Towards Photocatalytic Dyads for Hydrogen Production, in the Journal: (JOURNAL)
  • what: In this report we describe a new strategy to obtain [FeFe]-hydrogenase synthetic mimics stabilised by peri-substituted naphthalene dithiolate or diselenolate ligands which also contain basic nitrogen functionality in close proximity to the catalytically active_site.
  • how: The same observation can be made for the oxidation processes (except for the first oxidation of 4 and 5).

SUMMARY

    The . . .

     

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