Oxidative cyclization of aldehyde thiosemicarbazones induced by potassium ferricyanide and by tris( p -bromophenyl)amino hexachloroantimoniate. a joint experimental and computational study

HIGHLIGHTS

• who: hussam from the (UNIVERSITY) have published the article: Oxidative cyclization of aldehyde thiosemicarbazones induced by potassium ferricyanide and by tris( p -bromophenyl)amino hexachloroantimoniate. A joint experimental and computational study, in the Journal: (JOURNAL)
• what: The study provides a detailed picture of the reaction mechanism for the oxidative cyclization of aldehyde thiosemicarbazones.
• how: As a second step the authors evaluated the relative reactivities of the substrates by means of suitable competitive experiments (see experimental). To evaluate the secondary isotope effect for the deuteriated compound 1a(D) its relative reactivities towards substrates 1d . . .
  

   

  

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