Relationship between network topology and negative electrode properties in wadsley–roth phase tinb2o7

HIGHLIGHTS

• What: The authors investigated the effect of the network structure (intermediate-range structure) which is considered to form Li+ conduction pathways on the electrode properties of TiNb2O7. Considering the above situation, to clarify the relationship between the negative electrode properties and the atomic configuration of Wadsley-Roth phase TiNb2O7, the material was prepared via different methods in this study, and the negative electrode properties were evaluated via galvanostatic charge/discharge cycle tests. In this study, free spaces in the atomic configurations were calculated using Structural Order Visualization and Analysis (SOVA) tools developed by Shiga and a coworker38 . . .
  

   

  

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