HIGHLIGHTS
- who: Wang et al. from the University of have published the paper: Selective Coupling of 1,2‐Bis‐Boronic Esters at the more Substituted Site through Visible‐Light Activation of Electron Donor-Acceptor Complexes, in the Journal: (JOURNAL)
- what: Usually, the less hindered primary boronic ester reacts, but herein, the authors report a coupling reaction that enables the reversal of this selectivity. The advantage of exploiting EDA complexes is their ability to undergo PET in the absence of photocatalysts, therefore the proposed deboronative arylation should proceed under catalyst-free conditions.[11] Herein, the authors demonstrate . . .
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