Rac -carbonyl{1-[(diphenylphosphino)- methyl]ethanethiolato}(triphenyl- phosphine)rhodium(i)

HIGHLIGHTS

  • who: Experimental and collaborators from the InstitutUniversidad Nacional Autou0301noma Ciudad Universitaria, Mu00e9xico, Mexico have published the paper: rac -Carbonyl{1-[(diphenylphosphino)- methyl]ethanethiolato}(triphenyl- phosphine)rhodium(I), in the Journal: (JOURNAL) of 24/09/2008

SUMMARY

    The title compound,, was synthesized from the reaction of the ligand rac-[Ph2PCH2CH(CH3)SH] with trans-[Rh(F)(CO)(PPh3)2] in a 1:1 molar ratio in toluene. The Rh atom is four-coordinated in a distorted square-planar geometry with the P-S ligand acting as a chelate and the PPh3 and disordered CO . . .

     

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