HIGHLIGHTS
SUMMARY
Recent measurements of the IR spectrum of the Eigen cation (H9 O4+ ) reveal a strong coupling between the O-H stretch modes of the central hydronium unit with the water molecules in its first solvation shell. More importantly, they reveal strong shifts of the spectral position of the core O-H stretch modes caused by the polarization through the tagging agent in the second solvation shell9. The key to understanding the anharmonic couplings of the core O-H stretch modes to their first solvation shell lies in characterizing the broadening and composition of the . . .
If you want to have access to all the content you need to log in!
Thanks :)
If you don't have an account, you can create one here.