HIGHLIGHTS
- who: Angewandte et al. from the (UNIVERSITY) have published the paper: Gauging Radical Stabilization with Carbenes, in the Journal: (JOURNAL)
- what: With the large variety of C-donor ligands experimentally investigated and their electronic properties established the authors report herein their radicalstabilizing effect. The authors show that radical stabilization can be understood by a captodative frontier orbital description involving u03c0-donation to- and u03c0-donation from the This picture sheds a new perspective on NHC chemistry where u03c0-donor effects usually are assumed to be negligible. The authors show how to understand and predict their . . .
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