Mechanistic insights into photochemical nickel-catalyzed cross-couplings enabled by energy transfer

HIGHLIGHTS

  • who: Rajesh Kancherla from the King Abdullah University of (KAUST), Thuwal, Kingdom of Saudi Arabia have published the research: Mechanistic insights into photochemical nickel-catalyzed cross-couplings enabled by energy transfer, in the Journal: NATURE COMMUNICATIONS NATURE COMMUNICATIONS
  • what: Demonstrating the viability of EnT processes, the authors report a method for the direct crosscoupling of u03b1-oxy C(sp3)-H bonds with alkyl bromides to give C(sp3)-C(sp3) coupled products using a sensitized nickel catalyst with both experimental and computational support (Fig 2c).
  • how: The study highlights that for photochemical/metal . . .

     

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