Enzyme-catalyzed allylic oxidation reactions: a mini-review

HIGHLIGHTS

  • who: August et al. from the University of Murcia, Spain have published the research: Enzyme-catalyzed allylic oxidation reactions: A mini-review, in the Journal: (JOURNAL)
  • what: In this study (Zhang et_al, 2017), a very unique pathway for the biosynthesis of pentacyclic triterpenes was presented.
  • how: Many results showed that the hydroxylation reaction preferentially occurred in the free methylene groups (Gutiu00e9rrez et_al 2011 Peter et_al 2011 Kluge et_al 2012). Earlier results showed that wild-type UPOs catalyzed linear alkenes with a preference for allylic hydroxylation reaction but showed low chemoselectivity toward branched and . . .

     

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