HIGHLIGHTS
- who: Chenhuan Zhang from the (UNIVERSITY) have published the research: Ni-catalyzed carbamoylation of unactivated alkenes for stereoselective construction of six-membered lactams, in the Journal: (JOURNAL) of 14/07/2022
- what: The authors report the unprecedented 6-exo-trig cyclized carbamoylation by the utilization of the nickel-catalyzed asymmetric reductive difunctionalization of alkenes strategy.
SUMMARY
The transition metal-catalyzed asymmetric carbamoylation has been widely employed as a straightforward arsenal for chiral lactam architecture synthesis, including β-lactam and γlactam. In this manuscript, the Nicatalyzed enantioselective carbamoylation of unactivated alkenes by the . . .
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