HIGHLIGHTS
SUMMARY
Rhenium has recently attracted renewed attention in medicine due to its increasing potential applications in the anticancer arena. In this respect, hydrophilic ligands could exert the same role with minimal disruption of the complexes` structural identity. The nitrogen atoms are reactive under specific conditions, enabling its functionalization (e_g, N-alkylation) and thus, it could be used as a starting point for targeted drug design by tethering biologically active molecules. Concerning fa + complexes, PTA is coordinated to the metal centre either in combination with other monodentate ligands (e_g, Cl and Br) or as part of . . .
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