HIGHLIGHTS
- who: Communications et al. from the (UNIVERSITY) have published the article: Copper(I) Photocatalyzed Bromonitroalkylation of Olefins: Evidence for Highly Efficient Inneru2010Sphere Pathways, in the Journal: (JOURNAL)
- what: The authors report the visible light-mediated coppercatalyzed vicinal difunctionalization of olefins utilizing bromonitroalkanes as ATRA reagents.
SUMMARY
Late-stage functionnalization of biologically active molecules and upscaling to gram quantities is demonstrated, which offers manifold possibilities for further transformations, e_g access to nitro- and aminocyclopropanes. CuI photocatalyzed ATRA reactions. ability of CuII, being a persistent radical, to interact with a transient radical to . . .
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