Electronic modulation of metal-support interactions improves polypropylene hydrogenolysis over ruthenium catalysts

HIGHLIGHTS

  • who: Pavel A. Kots from the (UNIVERSITY) have published the paper: Electronic modulation of metal-support interactions improves polypropylene hydrogenolysis over ruthenium catalysts, in the Journal: (JOURNAL) of 24/08/2022
  • what: The authors demonstrate that combining deuterium nuclear magnetic_resonance spectroscopy with temperature variation and density functional theory can reveal the complex nature, binding strength, and H amount. The authors show that extensive reduction of TiO2 via hydrogen spillover from Ru modifies the hydrogen storage capacity of the Ru nanoparticles. The authors propose that the different nature of chemisorbed hydrogen may be partially responsible for . . .

     

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