Catalytic enantioselective synthesis of n-c axially chiral n-(2,6-disubstituted-phenyl)sulfonamides through chiral pd-catalyzed n-allylation

HIGHLIGHTS

• who: Sota Fukasawa and collaborators from the Department of Applied Chemistry (Japanese Association of Bio-Intelligence for Well-Being) have published the paper: Catalytic Enantioselective Synthesis of N-C Axially Chiral N-(2,6-Disubstituted-phenyl)sulfonamides through Chiral Pd-Catalyzed N-Allylation, in the Journal: Molecules 2022, 7819 of /2022/
• what: The authors report the catalytic synthesis of N-C axially

SUMMARY

Atropisomers (N-C axially chiral_compounds), owing to the rotational restriction around an N-C single bond, have recently attracted much attention. The N-allylation reaction shown in Scheme . . .

 



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