Online membrane sampling for the mass spectrometric analysis of oil sands process affected water-derived naphthenic acids in real-world samples

HIGHLIGHTS

SUMMARY

    The oil sands in Northern Alberta, Canada represent the fourth largest oil deposit in the world, with over 165 billion projected barrels of oil recoverable. Basic transfer solvent appeared to favor classical O2 -NAs, so to further improve CP-MIMS selectivity to O2 -NAs the authors added 0.1% NH4 OH (v/v) post-membrane and collected HRAM spectra for the 2018 and 2015/2 extracts. Analysis naphthenic acids inherently challenging analytical task due Analysis ofof naphthenic acids is is anan inherently challenging analytical task due to to thethe complexity of the analyte class . . .

     

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