HIGHLIGHTS
- who: Giese radical addition and colleagues from the Organic Chemistry Department, Módulo, Universidad Autónoma de Madrid, Madrid, Spain have published the research work: Remote Giese Radical Addition by Photocatalytic Ring Opening of Activated Cycloalkanols, in the Journal: (JOURNAL)
SUMMARY
The addition of transient alkyl radicals to electron deficient double bonds, known as the Giese reaction, is a well Adv. Synth. This method has been employed for the arylation,[10a] halogenatio and allylatio of ketones in remote positions. After intensive optimization of the reaction conditions, 5 mol% of the ClO4 as photo . . .
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