A modular approach to atropisomeric bisphosphines of diversified electronic density on phosphorus atoms

HIGHLIGHTS

  • who: Oleg M. Demchuk and colleagues from the Institute of Biological Sciences, Faculty of Science and Health, The John Paul II Catholic University of Lublin, Konstantynów J/403, Lublin, Poland have published the paper: A Modular Approach to Atropisomeric Bisphosphines of Diversified Electronic Density on Phosphorus Atoms, in the Journal: Molecules 2022, 5504 of /2022/
  • what: We have designed and synthesized atropisomer 4,40,6,60 -tetramethyl biaryls bearing phosphorus functionalities at 2,20 -positions and different substituents at 5,50 -positions from one universal non-racemic 5,50 -diamine substituted precursor DIDAB.
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