Oxalate decarboxylase uses electron hole hopping for catalysis

HIGHLIGHTS

  • who: Anthony J. Pastore from the Anthony JPastore1, Ruijie D. Teo2, Alvaro Montoya1, Matthew J. Burg1, Umar T. Twahir1, Steven D. Bruner1, David N. Beratan2, *, and Alexander Angerhofer1, * From the Department of Chemistry, University of Florida, Gainesville, Florida, USA have published the Article: Oxalate decarboxylase uses electron hole hopping for catalysis, in the Journal: (JOURNAL) of February/20,/2021
  • what: As the authors demonstrate here, such a hopping pathway does indeed exist via the π-stacked W96/ W274 pair within the hexameric cluster found in the reported OxDC crystal_structures (see Fig 1B). To kcat and KM . . .

     

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