Nucleation of mercury sulfide by dealkylation

HIGHLIGHTS

  • who: Mironel Enescu from the LaboratoireUniversity of, CS, Grenoble, France have published the article: Nucleation of mercury sulfide by dealkylation, in the Journal: Scientific Reports Scientific Reports

SUMMARY

    | 6:39359 | RS‐(Hg‐S)n ‐R + RS‐Hg‐SR → RS‐(Hg‐S)n +1‐R + R‐S‐R. Given that β​-HgS also was obtained from Hg-dicysteinate complexes (Hg(Cys)2), the R group in natural organic matter can be an alkyl ligand of the general form CH2-R'. The authors present quantum chemical calculations of the structure and energetics of the transition_state in . . .

     

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