Alkynyl ligands as building blocks for the preparation of phosphorescent iridium(iii) emitters: alternative synthetic precursors and procedures

HIGHLIGHTS

  • who: Vadim Adamovich and colleagues from the (UNIVERSITY) have published the article: Alkynyl Ligands as Building Blocks for the Preparation of Phosphorescent Iridium(III) Emitters: Alternative Synthetic Precursors and Procedures, in the Journal: (JOURNAL) of April/19,/2022

SUMMARY

    The stabilization of dimers 2 with a cis disposition of the heterocycles of the 3b ligands is a target of prominent importance for the field. The substituent of the C-C triple bond can govern the contribution of the σligand-to-metal, π-metal-to-ligand, and π-ligand-to-metal bonding components to the metal . . .

     

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