Amine‐catalyzed copper‐mediated c−h sulfonylation of benzaldehydes via a transient imine directing group**

HIGHLIGHTS

  • who: Angewandte et al. from the (UNIVERSITY) have published the research work: Amineu2010Catalyzed Copperu2010Mediated Cu2212H Sulfonylation of Benzaldehydes via a Transient Imine Directing Group**, in the Journal: (JOURNAL)
  • what: The authors report the first use of TDG in combination with copper to effect Initially, the authors aimed to establish whether copper mediated C H functionalization reactions were feasible with a catalytic TDG. The simple imine formation was unlikely to be the cause of inhibition, therefore, the authors propose that the inhibitory effect arises from the formation of a copper ligated imine intermediate involving the sulfonyl . . .

     

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