An aminative rearrangement of o‐(arenesulfonyl)hydroxylamines: facile access to ortho‐sulfonyl anilines

HIGHLIGHTS

• who: Zuschriften and collaborators from the (UNIVERSITY) have published the research work: An Aminative Rearrangement of Ou2010(Arenesulfonyl)hydroxylamines: Facile Access to orthou2010Sulfonyl Anilines, in the Journal: (JOURNAL)
• what: The authors report the discovery of an aromatic rearrangement reaction of O(arenesulfonyl)hydroxylamines which leads directly to ortho-sulfonyl anilines through formation of a new C N bond with excellent levels of regiocontrol for the ortho position(s) over all others. The authors disclose a complementary disconnection that provides rapid access to this important class of compounds, which installs the C N bond rather than . . .
  

   

  

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