Anion-controlled synthesis of novelguanidine-substituted oxanorbornanes

HIGHLIGHTS

  • who: Luka Bareu0161iu0107 et al. from the Laboratory for Physical Organic Chemistry, Division of Organic Chemistry and Biochemistry have published the article: Anion-Controlled Synthesis of NovelGuanidine-Substituted Oxanorbornanes, in the Journal: (JOURNAL)
  • what: In this work, the impact of the anion selection on the discrimination between the cycloaddition and aza-Michael addition as a typical concurrent reaction is described .
  • how: With that in mind the NMR experiment was conducted in which the oxanorbornadiene 4bu00b7HPF6 (crude product) was effectively cyclized upon the addition of the phosphazene base P1*tBu confirming deprotonation as the . . .

     

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