Aryl acrylonitriles synthesis enabled by palladium-catalyzed α -alkenylation of arylacetonitriles with vinyl halides/tri fl ates

HIGHLIGHTS

• who: December et al. from the Qujing Normal University, China have published the research: Aryl acrylonitriles synthesis enabled by palladium-catalyzed u03b1 -alkenylation of arylacetonitriles with vinyl halides/tri fl ates, in the Journal: (JOURNAL)
• what: The authors report an efficient synthesis of aryl acrylonitrile derivatives using a Palladium/NIXANTPHOSbased catalyst system.
• how: L1 NIXANTPHOS L2 XANTPHOS L3 PPh3 L4 P (o-TOL)3 L5 P (1-NAP)3 L6 rac-BINAP L7 JOHNPHOS L8 PCy3 B1 LiN(SiMe3)2 B2 NaN(SiMe3)2 B3 KN(SiMe3)2 B4 t LiO Bu B5 . . .
  

   

  

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