Asymmetric hydrogenation of 1,1-diarylethylenes and benzophenones through a relay strategy

HIGHLIGHTS

• who: Ke Li from the (UNIVERSITY) have published the Article: Asymmetric hydrogenation of 1,1-diarylethylenes and benzophenones through a relay strategy, in the Journal: (JOURNAL) of 29/03/2023
• what: The authors report a relay strategy for constructing compounds with a chiral gem-diaryl carbon center by means of a combination of selective arene exchange between 1,1-diarylethylenes or benzophenones with (naphthalene)Cr(CO)3 and subsequent asymmetric hydrogenation.
• how: Next the authors investigated the asymmetric hydrogenation of Cr(CO)3ligated 1a as a model substrate by using various chiral Ru . . .
  

   

  

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