Carbenes in synthesis and homogeneous catalysis

HIGHLIGHTS

• who: Crabtree R. H. from the Yale Chemistry Dept, Prospect St, New Haven, CT, , USA have published the research work: Carbenes in Synthesis and Homogeneous Catalysis, in the Journal: (JOURNAL)
• what: The present review provides a few examples from the own group showing how careful ligand design is needed to facilitate chelation in NHCs and how the resulting complexes can be useful in catalysis.

SUMMARY

Homogeneous catalysis by transition metal complexes has transformed both industrial and organic synthetic chemistry in many ways. The best example (Fig 1) is the NHC-modified . . .

 



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