Carbodefluorination of fluoroalkyl ketones via a carbene-initiated rearrangement strategy

HIGHLIGHTS

  • who: Linxuan Li from the Department of Chemistry, Northeast Normal University, Changchun, China Department of Chemistry, University of Pavia, Viale Taramelli, have published the article: Carbodefluorination of fluoroalkyl ketones via a carbene-initiated rearrangement strategy, in the Journal: (JOURNAL) of 12/07/2022

SUMMARY

    After cooling to room temperature, unreacted pyrazole was removed by vacuum sublimation (150 °C, 2 mbar) to give TlTpBr3 as a white solid. General procedure carbodefluorination reaction of indole-3carbinols To a dried sealed tube was charged with N-tfsylhydrazone (0.3 mmol, 1.0 equiv), indole-3-carbinol . . .

     

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