Change in the electronic structure of the cobalt(ii) ion in a one-dimensional polymer with flexible linkers induced by a structural phase transition “2279

HIGHLIGHTS

SUMMARY

Modulation of the spin state can be caused by co-crystallization involving halogen bonds, the appearance of interligand π-stacking, as well as the presence of hydrogen_bonds between the ligands. Despite the close values of the a,b,c-parameters and Despite the close values of the a,b,c-parameters and the unit cell volumes of the γ-1 and δthe unit cell volumes of the γ-1 and δ-1 phases, they differ in α,β,γ-angles, which indicates 1 phases, they differ in α,β,γ-angles, which indicates the uniqueness of the δ-1 phase (Tathe uniqueness of the δ-1 . . .

 



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