HIGHLIGHTS
- who: Josu00e9 Manuel Gonzu00e1lez and colleagues from the (UNIVERSITY) have published the Article: Chiral Ligands Based on Binaphthyl Scaffolds for Pd-Catalyzed Enantioselective C-H Activation/Cycloaddition Reactions, in the Journal: (JOURNAL) of November/15,/2022
- what: The authors report the first examples of the use of a new class of ligands (NOBINAc) for performing asymmetric C-H activations using palladium catalysts. The authors demonstrate that the new ligands enable substantially higher enantioselectivities than MPAAs in the assembly of 2-benzazepines through formal (5 + 2) cycloadditions between homobenzyltriflamides or o-methylbenzyltriflamides and allenes.
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