Comprehensive and practical guidelines for reduction synthesis of atomically precise coinage–metal nanoclusters

HIGHLIGHTS

  • What: After examining over 200 synthetic examples of individual metal NCs prepared through direct reduction methods-using reactants such as single metals (Au Ag and Cu) or alloys (e_g Au-Ag Au-Pt) along with ligands such as phosphines thiolates and alkynyls N-heterocyclic carbenes halides and their combinations the authors propose comprehensive and practical guidelines for the reduction synthesis of ligand-stabilized metal NCs. review aims to elucidate the potential introduction of robust synthetic prototypes for engineering these NCs which have evolved from one-phase two-phase and miscible solution synthesis to solidstate synthesis. This approach . . .

     

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