Cooperative light-induced breathing of soft porous crystals via azobenzene buckling

HIGHLIGHTS

  • who: Simon Krause from the Stratingh Institute University of have published the research: Cooperative light-induced breathing of soft porous crystals via azobenzene buckling, in the Journal: NATURE COMMUNICATIONS NATURE COMMUNICATIONS
  • what: The authors demonstrate the design and analysis of DUT163, a MOF with framework-embedded azobenzene photoswitch. The authors show that the light activation is applied locally allowing to use this process in light-responsive nanoscopic pneumatic systems and gas-releasing devices. Rather than E-Z isomerization which would cause pronounced changes in the PXRD patterns as well as Raman and DRIFT spectra, the . . .

     

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