Crystal structure of tert-butyl-n-phenylcarbonitrilium tetrachloridoaluminate

HIGHLIGHTS

  • who: CCDC reference and collaborators from the Department of Chemistry and Pharmaceutical Sciences, VU University Amsterdam, De Boelelaan, HVInternational BV, The Netherlands have published the Article: Crystal structure of tert-butyl-N-phenylcarbonitrilium tetrachloridoaluminate, in the Journal: (JOURNAL)

SUMMARY

    Interestingly, nitrilium tetrachloridoaluminates, which can be synthesised using the much cheaper AlCl3, have found little application (Meerwein, Laasch, Mersch and amp; Spille, 1956; Al-Talib et_al 1992). The nitrilium cation adopts a slightly distorted linear configuration and features an N C bond length of 1.1353 Å, which is in the range of previously . . .

     

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