Diastereodivergent synthesis of cyclopentyl boronic esters bearing contiguous fully substituted stereocenters

HIGHLIGHTS

• who: Fairchild and colleagues from the University of have published the research work: Diastereodivergent Synthesis of Cyclopentyl Boronic Esters Bearing Contiguous Fully Substituted Stereocenters, in the Journal: (JOURNAL)
• what: The authors report the electrophile-induced ring contractive 1,2-metallate rearrangement of 6-membered cyclic alkenyl boronate complexes for the synthesis of cyclopentyl boronic esters bearing two contiguous, fully substituted stereocenters with high levels of stereocontrol.

SUMMARY

The authors report the electrophile-induced ring contractive 1,2-metallate rearrangement of 6-membered cyclic alkenyl boronate complexes for the synthesis of cyclopentyl . . .

 



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