Direct observation of the dynamics of ylide solvation by hydrogen-bond donors using time-resolved infrared spectroscopy

HIGHLIGHTS

  • who: Ryan Phelps and Andrew J. Orr-Ewing from the University of Bristol, Explore Bristol Research have published the research: Direct Observation of the Dynamics of Ylide Solvation by Hydrogen-bond Donors Using Time-Resolved Infrared Spectroscopy, in the Journal: (JOURNAL) of May/17,/2022
  • what: Using band shifts observed by TRIR, the authors present direct spectroscopic evidence for specific solvent interactions between EDA-derived THF ylides (THF-Y) and ethanol (EtOH), chloroform, dichloromethane (DCM), ACN, and cyclohexane HB donors, and the authors characterize the kinetics of solvation. The authors focus on the solvent-mediated . . .

     

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