Diverse synthesis of α-tertiary amines and tertiary alcohols via desymmetric reduction of malonic esters

HIGHLIGHTS

• who: Haichao Liu from the State Key Laboratory of Synthetic Chemistry, Department of Chemistry, The University of Hong Kong, Hong Kong, China have published the research: Diverse synthesis of α-tertiary amines and tertiary alcohols via desymmetric reduction of malonic esters, in the Journal: (JOURNAL) of 11/04/2022
• what: The authors show that a suite of pipecolinol-derived tetradentate ligands can accommodate various types of nitrogen-/oxygen-substituted malonic esters to deliver the enantioenriched hydrosilylation products.

SUMMARY

While conventional methods towards these motifs often rely on enantioselective carbon-carbon or carbonheteroatom . . .

 



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