Effect of mono- and multichlorinated organic compounds—chlorocyclohexane and hexachloro-p-xylene—on the catalytic properties of titanium-magnesium catalysts in the homo- and copolymerization of ethylene with 1-hexene

HIGHLIGHTS

• who: Ildar I. Salakhov et al. from the RandD Center PJSC Nizhnekamskneftekhim, Nizhnekamsk, Russia have published the Article: Effect of Mono- and Multichlorinated Organic Compoundsu2014Chlorocyclohexane and Hexachloro-p-xyleneu2014On the Catalytic Properties of Titanium-Magnesium Catalysts in the Homo- and Copolymerization of Ethylene with 1-Hexene, in the Journal: (JOURNAL)
• what: The promoters analyzed in this study had no effect on the thermal properties of polyethylene formed over TMC.

SUMMARY

Halogenated hydrocarbons can be weakly coordinated to the titanium active_site, thus changing its reactivity. This may block some of the active_sites . . .

 



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