HIGHLIGHTS
- What: The authors report under acidic conditions which are expected to proceed via cations generated by single-electron oxidation of alkenes.
- Who: Sota Adachi and Yohei Okada from the Department of Applied Biological Science, University of, Japan have published the research: Electrochemical radical cation aza-Wacker cyclizations, in the Journal: (JOURNAL)
SUMMARY
A radical cyclization generates a five-membered ring with a less-stable primary radical, while a six-membered ring with a secondary cation is obtained through ionic cyclization. When such intra- molecular cyclizations are expected to proceed via radical . . .
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