Enantiocontrolled preparation of -substituted cyclohexenones: synthesis and kinase activity assays of cyclopropyl-fused cyclohexane nucleosides

HIGHLIGHTS

• who: Sergio Jurado and collaborators from the Universitat Autu00f2noma Barcelona, Bellaterra, Barcelona, Spain have published the article: Enantiocontrolled Preparation of -Substituted Cyclohexenones: Synthesis and Kinase Activity Assays of Cyclopropyl-Fused Cyclohexane Nucleosides, in the Journal: (JOURNAL) of 26/08/2022
• what: In this article, an easy route to enantiomerically pure 4-hydroxy-2-cyclohexanone derivatives 1a,b, which are commonly used as chiral building blocks, was identified on the basis of ATH with bifunctional ruthenium catalysts. This approach provided convenient access to both enantiomers from the same precursor by selecting either the (S,S)- or . . .
  

   

  

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