HIGHLIGHTS
SUMMARY
The amine group is a common constituent of red/near-infrared dyes because it promotes intramolecular charge transfer (ICT) in the electronic excited_state which is mechanistically more efficient in reducing the electronic transition energy gaps than expanding π-conjugation in hydrocarbons. In recent decades, researchers havearray expanded attention to more molecular and as a twis and examined a wider of structures, particularly with thescaffolds amine group examined a wider array of structures, particularly with the group a twisting to analog unit, to elucidate the properties of TICT.amine Though the molecules with an emissive TICT . . .
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