Gas phase synthesis of [4]-helicene

HIGHLIGHTS

  • who: Long Zhao from the University of have published the research work: Gas phase synthesis of [4]-helicene, in the Journal: NATURE COMMUNICATIONS NATURE COMMUNICATIONS
  • what: This study provides evidence that the simplest representative of the class of helicenes, i.e., -helicene, can be formed in a directed synthesis through the gas phase elementary reaction of the 4-phenanthrenyl radical with vinylacetylene. The ions formed via soft photoionization in the present experiments are extracted and introduced onto a microchannel plate detector through an ion lens.

SUMMARY

    A single transition_state with C2v . . .

     

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