Gold(i) -trifluoromethyl carbenes: synthesis, characterization and reactivity studies

HIGHLIGHTS

  • who: Mathilde Rigoulet and collaborators from the (UNIVERSITY) have published the research: Gold(I) -Trifluoromethyl Carbenes: Synthesis, Characterization and Reactivity Studies, in the Journal: (JOURNAL)
  • what: Using an (o-carboranyl)diphosphine ligand, we have been able to prepare and fully characterize u03b1-CF3 gold(I) carbenes.
  • future: Gratifyingly crystals suitable for X-ray diffraction analysis could be obtained in this cas unambiguously confirming the addition of the N-Lewis base to the carbene center (Scheme 2 bottom).

SUMMARY

    The interplay of gold and fluorine, two peculiar elements within the . . .

     

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