Hexakis(2-amino-4-methylpyridine- j n )- dioxidohexa- l -sulfido-hexacopper(i)- divanadium(v)

HIGHLIGHTS

  • who: Experimental and colleagues from the DepartmentPeople's Republic of China have published the research work: Hexakis(2-amino-4-methylpyridine- j N )- dioxidohexa- l -sulfido-hexacopper(I)- divanadium(V), in the Journal: (JOURNAL) of 23/08/2008

SUMMARY

    The title compound,, is constructed from six CuS3N and two VOS3 distorted tetrahedra, forming an octanuclear V/S/Cu cluster with Ci symmetry. The geometry around the V atoms is slightly distorted tetrahedral, while there are large distortions from ideal tetrahedral geometry for the Cu atoms. Adjacent metal-metal distances range from 2.693 . . .

     

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