Instanton formulation of fermi’s golden rule in the marcus inverted regime

HIGHLIGHTS

  • who: Eric R. Heller and colleagues from the Laboratory of Physical Chemistry, ETH Zürich, Zürich, Switzerland have published the research work: Instanton formulation of Fermi’s golden rule in the Marcus inverted regime, in the Journal: (JOURNAL)
  • what: The authors propose an extension of the semiclassical instanton method51-53 for the inverted regime in the golden-rule limit. The authors show excellent agreement with the exact golden-rule rates for the model systems studied. The aim of the semiclassical instanton approach is to obtain a good approximation to the golden-rule rate without . . .

     

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