Intense molar circular dichroism in fully conjugated all‐carbon macrocyclic 1,3‐butadiyne linked pseudo‐meta [2.2]paracyclophanes

HIGHLIGHTS

• who: E. Sidler et al. from the Department of Chemistry University of Basel StJohanns-Ring, Basel, Switzerland have published the paper: Intense Molar Circular Dichroism in Fully Conjugated Allu2010Carbon Macrocyclic 1,3u2010Butadiyne Linked pseudou2010meta [2.2]Paracyclophanes, in the Journal: (JOURNAL)
• what: The authors report the synthesis characterization and optical properties of four novel all-carbon enantiopure macrocycles bearing three to six pseudo-meta PCPs linked by 1 3-butadiyne units. By comparing the optical properties to relevant reference compounds the authors show that the pseudo-meta PCP subunit effectively elongates the conjugated system throughout . . .
  

   

  

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