Interplay of diruthenium catalyst in controlling enantioselective propargylic substitution reactions with visible light-generated alkyl radicals

HIGHLIGHTS

  • who: Yulin Zhang from the (UNIVERSITY) have published the paper: Interplay of diruthenium catalyst in controlling enantioselective propargylic substitution reactions with visible light-generated alkyl radicals, in the Journal: (JOURNAL) of 18/Oct/2022
  • what: The authors show the preparation of propargylic alkylated products with a chiral carbon center at the propargylic position via the enantioselective propargylic substitution reaction with free_radicals, where the reactivity of radicals is well governed by the dual photoredox- and diruthenium-catalyzed system, providing the successful example of enantioselective propargylic substitution reaction with free_radicals. The authors believe this work provides another . . .

     

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