Large amplitude motion in cold monohydrated dihydrogen phosphate anions h po (h o): infrared photodissociation spectroscopy combined with ab initio molecular dynamics simulations †

HIGHLIGHTS

• who: PCCP from the (UNIVERSITY) have published the research: Large amplitude motion in cold monohydrated dihydrogen phosphate anions H PO (H O): infrared photodissociation spectroscopy combined with ab initio molecular dynamics simulations †, in the Journal: (JOURNAL)
• what: The IRMPD spectra of H2PO4 (H2O) show evidence for isomerization even at cryogenic temperatures, wherein the clusters undergo large amplitude motion over a small barrier.
• how: The DTCF spectrum at 180 K indeed reproduces a broad feature centered at 3161 cm 1 near the experimental peak E. This feature is also observed in the 140 K . . .
  

   

  

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