Mechanism of the aryl-f bond-forming step from bi(v) fluorides

HIGHLIGHTS

  • who: Oriol Planas and collaborators from the (UNIVERSITY) have published the Article: Mechanism of the Aryl-F Bond-Forming Step from Bi(V) Fluorides, in the Journal: (JOURNAL) of January/27,/2022
  • what: Pubs.acs.org/JACS Herein, the authors report a mechanistic study aimed at providing a detailed analysis of the aryl-F reductive elimination event from u03c3-aryl Bi(V) fluoride species. The authors assess the role of electronic and geometric perturbations on the ligand scaffold in 1, as well as on the pendant aryl moiety, with the aim of identifying the steric . . .

     

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