Mer-hydridotris(trimethylphosphane-[kappa]p)(d-valinato-[kappa]2n,o)iridium hexafluoridophosphate dichloromethane 0.675-solvate

HIGHLIGHTS

  • who: Experimental and colleagues from the Department of Chemistry, Virginia Tech, Blacksburg, VA, USA have published the article: mer-Hydridotris(trimethylphosphane-[kappa]P)(d-valinato-[kappa]2N,O)iridium hexafluoridophosphate dichloromethane 0.675-solvate, in the Journal: (JOURNAL) of 21/01/2014

SUMMARY

    The title compound, PF60.675CH2Cl2, an iridium compound with a meridional arrangement of PMe3 groups, O,N-bidentate coordination of d-valine and with a hydride ligand trans to the N atom is compared with the l-valine complex reported previously. As expected, the complexes from the corresponding l and . . .

     

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