HIGHLIGHTS
- who: Sebastien Curpanen et al. from the IPCM, Place Jussieu, Paris, France have published the paper: Modular synthesis of 2-furyl carbinols from 3-benzyldimethylsilylfurfural platforms relying on oxygen-assisted C-Si bond functionalization, in the Journal: (JOURNAL)
- what: Conversely, this experiment provided evidence that cyclic siloxanes (e_g, 16), which are potential nucleophilic partners for cross-coupling chemistry , could be accessed from 2-[(3benzyldimethylsilyl)furyl] carbinols.
- how: Similar results were obtained using the preformed complex CuIu22c5PPh3 (1.5 equiv) so that compound 21 could be isolated in 65% yield .
SUMMARY
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